These two moments in Prince songs get me everytime - they're just AWESOME.

I Could Never Take The Place Of Your Man
5m51s - 6m03s (that shimmering guitar as we are launched back into the melody).

Little Red Corvette (12-inch version)
5m13s - 5m40s (that added bass-line kicks in specially for this version).

Neither of these moments appear on "The Hits" compilation edits of the songs.

Damn shame.